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Yes adding to much P.H up or down would eventually harm your plants. It's because of the conductivity of the nutrient solution after adding nutes why you need to add so much P.H adjuster to try and balance it out. When adding any P.H up/down you should use a coffee cup or similer and test a cup...

Hi I have used canna pk 13-14 and it worked great for me. Budz really bulked up ,smelt alot fresher and trichomes started ambering . I used it for last 2 weeks of flower and then flushed for 7 days great results. Pineapple chunk. Flowered in 9 weeks.

I'd give em a few more days .. Check out these pics , shows the difference between ready or not. The trichomes should be tinted amber. link - https://www.rollitup.org/harvesting-curing/28072-harvest-time-tutorial.html