You should be taking temps at the canopy level or the tops of the plants.
This is true.
More CO2 Will not solve the problem nor will it hurt you in any case here. However if the plants are too warm more CO2 will be wasted since the plant will be using it's stoma to transpire which cools the plant. The reason you do not want your plant to get too warm is that the stoma is used to exchange gases and in this plant is primarily located on the underside of the leaves. This is where the plant will exchange water inside the plant as gas for CO2 and other parts of the air outside the plant.
So basically when your plant gets hot it sweats, dry air increases the effectivness of that sweating (transpiration).
Things to consider is that the warmer it is the faster the cycles will be carried out inside the plant as far as ATP and sugar production. However it comes to a point where you are getting TOO warm and the plant needs to cool itself down, if it devotes too many of it's stoma to transpiration it will not be bringing in as much CO2 (and other gases) which will be bringing ATP and sugar production to a crawl.
So at 93 with 35% you are probably fine to survive the whole lifespan, but will they be as good as they could? I really don't know enough to answer. I know how plants work inside but I havent done any extensive research myself on temperature, perhaps looking for a real case study on tomatoes may be a valid option. Too bad the US doesn't grant research for MJ.