I would have just set it out to dry more. Moisture and mold/mildew go hand and hand. Let it dry and trim off the moldy parts of the bud.
By looking at you pictures, it looks like you buds are dense, definitely not airy. Definitely needed longer than 3 days, sometimes it seems like the outside is dry but it really isn't throughly dried. This is main problem newer growers have. Using the 2 step drying process before curing helps indentify those buds before they get moldy. You'd be suprised how good those brown bags work. The reason is becasue the bags allow moisture from inside the bud to be re-absorbed evenly throughout the entire bud, buds that you may have thought were pretty dry, after a day in the brown bags, may actually still have a high % of moisture. You'll recognize those buds quickly and be able to watch them closely in the bags or if they are really damp, lay them back out on the screen or re-hang them for another day. Best way to go IMO.
Seriously though, I don't think freezing them is going to help. I'm pretty sure mold spores can survive some seriously low temps, even below freezing. Here's a quote I found in an article about it. The only thing I read that can kill mold spores, other than chemicals, is extremely high temps.
It is true that mold growth rate deteriorates during winter. Molds prefer warm environment; rate of spore generation reduces when the temperature is low. However, molds do not die in cold weather. They stay dormant and wait for the right conditions for life to come.