Straight from the Grow Faq.
Raising hydroponic pH : (to make it more alkaline)
In hydroponics: use potassium silicate, provides silicon at an effective doseage.
In bioponics/hydro-organics: add small amounts of sodium bicarbonate or lime.
Lowering hydroponic pH : (to make it more acidic)
In hydroponics: use nitric acid during vegetative; phosphoric acid during flowering.