That is the flaw in the whole idea. As I have said before during hours of light plants take in as much light and transform it into energy as they can. During hours of light the plants will multitask, they will allocate energy to all functions, including saving energy for use during hours of darkness.
 
During hours of darkness plants stop multitasking and allocate all their stored energy to just a few primary functions and growth and THC production are two such primary functions. Because of that those functions are allocated more energy during the hours of darkness than they get during hours of light so they grow faster and more efficient and they produce more THC faster and more efficiently.
 
There is also the loss of THC to factor in by increasing the amount of light plants get while still tricking them into believing they are in an regular flowering time cycle.
 
Light degrades THC, one primary function of THC is to work like a sunscreen for the trichome-head to protect it from the suns/grow lights damaging rays. During hours of darkness when THC is produced more efficiently and at a faster rate the lost THC is replenished and then a small additional amount more is made so you have a slow gradual increase in THC levels by plant maturity.
 
But if you extend the hours of light when in the 12 hours of darkness what is the assurance that the plant will be able to make up for the additional amount of THC lost to light degradation and then on top of that still be able to produce the small additional amount of THC that should be produced?
 
By manipulating the time in such ways at what point might someone reach a point of diminishing returns and at what point might they go beyond just diminishing returns and end up with a net loss?
Did I miss something in the above or did you just say that you are planning on going from a 12/12 flowering lighting cycle to a 14/10 lighting cycle where the hours of darkness would be less than 12 hours long and you say; "In theory that should work too" or did you mean you will be going to a 14/12 lighting cycle and do away with the whole 24 hour day concept?