i let it set out for at least 24 hours before i use it some one said that was good enough if not let me know
phing the water?????? wtf..... if it's tap water and you live in the states it will be between 5.1 and 6.3 which is fine for your plants. it's regulated.
how close are your lights, have you transplanted recently, when do you water, any ferts, any air circulation.
when you set your water out overnight.... that is to reduce chlorine found in tap water.
you say it's your top leaves...
it's most likely nutrient deficiency, if it was lower leaves it would most likely be stress.
heat issues: if you spray your plants and there under hid lights or your grow room is over 92 degrees this can cause the water to burn spots on your leaves.
it could be any number of things.... all of which are answered in plant problems.... even if you might have to read a few to get what you need it's easier that way, well it is if the person having problems has pics so you can compare yours to them.