How big is your pot ?
I useally start mine out in Cup`s so they don't stay wet for too long, but yes misting the top soil is a good idea with small young seedlings
Will also make em wet under the leaves (where there pores is located) so its also like misting them at the same time, now I don't know how your humidity is, but seedlings do like it moist
And you don't want to "over water your small seedling with there small root net to start with either, so atleast don't over do it in the start, on the other hand you also want to water em good to make the hole pot/cup wet now and then, its a trail and run, and also depend a lot of the size of your pots, your temperature and RH, your medium and even light
A good thing to have around if you end up over watering them (witch actually is lack of oxygen in the medium) is hydrogen peroxide (the 3% works just fine)
http://hubpages.com/hub/Hydrogen-Peroxide-for-Plants
I like it when I have to water every 3-4 day, when they begin to dry out in less then 2 days and I have to water every day I like to repot em (this is in Veg and when all other factors is with in optimal conditions 24-26C and 50-60% RH) a big pot for a small seedling (etc 5 gallon) is often a bad idea if your not very careful and have a medium that drains well