Careful what you read in some of these posts. For one we are dealing with hydroponics not dirt so a Ph of 7 will kill your plants or lock everything up and they still die.
If your nutes are at 500ppm and two days later there at 350ppm you need to up your ppm! It works like this change res set ppm at say 600ppm ph 5.9 run for 24hrs, now if you ppm rise and ph drops nutes are to strong. If ppm drop and ph rises, nutes are to weak. But if your ppm and ph are basically stable then you have found the right mix for your plants.
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Then when topping off your res use pre mixed nutes to keep it at that level, if it starts to rise or fall adjust top off nutes as needed to bring it back to proper level. This is how I set my system up and has worked great for me
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People should be careful, you're right.
Your whole concept of PPM and pH fluctuation is all wrong, however.
PPM dropping does not necessarily raise the nutrient pH.
PPM rising does not necessarily lower the nutrient pH.
pH fluctuations occur for many reasons. It is not possible for most people to find some magic intersection of PPM and pH to keep both stable. Your personal pH and PPMs may be stable - I don't doubt that - but it is not because you found some ratio between the two. It has more to do with good nutrients, good make-up water. Consider yourself lucky.
There is so much more going on with water. For example, you could mix up a new batch of nutes, put them at 5.8pH and come back two hours later to have a pH of 8. This, as the artcile will explain to you below, happens if you have a bunch of dissolved CO2 or carbonic acid in your source water. I know this for a fact because my well is this way. It was a struggle to figure out why my water was super low or super high in pH at different times. Now I know to not adjust up EVER.. Especially when my source water goes through chemical changes that change the pH in mere hours.
Similarly, the alkalinity of the water has a HUGE effect on pH. And I don't mean acid/alkaline.. I mean total alkalinity, or carbonate content of the water. At pH below 8, the carbonates in your water are bi-carbonates or more precisely calcium bicarbonate (CaHCO3). The more of this that you have in your water, the more acid you have to dump in your reservoir to lower the pH. The pH will also rise alot even after you drop it down. This is the buffering effect of CAHCO3... It has nothing to do with the amount of nutrient plants are drinking..
Anyway, those are just two examples of why pH is so tricky.
If you want to read an article that touches on this stuff, check this out:
http://www.flairform.com/hints/water_quality.htm#Alkalinity (bicarbonate)
cheers