Going to need more than a spectrometer, going to need a Chromatograph...
Looks, and feels won't cut it...
I believe Berfelo on youtube has already shown that terpene production is more or it brings out terpenes which the HPS doesn't... Yeild per a watt on the LED's is obviously higher due to efficiency, however the lack of UVB is pointing to similar THC levels as HPS...
So, if Terpenes, and Phenols go through a photochemical or electromagnetic process to create THC then it wouldn't be far fetched to think LED+UVB may produce better buds. If you can pull 1.5gpw off of LEC then what is the push to 1.7 or 2 gpw on a LED...