Interesting, few links below but regardless I'm very much interested in the information you're referencing as I'd much like to read what you can link me.
The sulfur isotope composition of tholeiitic basalts, olivine alkali basalts and alkalirich undersaturated basalts were investigated. A method of preparation was devised (a) for the extraction of the small amounts of sulfur contained in the rock samples (about 100 ppm S), (b) for the separation...
link.springer.com
The concentration of S in basaltic magmas at 1 atm pressure is strongly dependent on temperature, the fugacities of oxygen (ƒO2) and sulfur (ƒS2), and…
www.sciencedirect.com
Just sources I've found in the past few years is all, still very interested in reading your sources as well though!
Gypsum (Calcium Sulfate) has a higher Sulfur content than Basalt, but also comes with the added Calcium content that can harm more than it helps in soil that already has Calcium inputs in it. If your water is heavily calcified such as my own, or your own particular soil blend is already high in Calcium content then you don't want to add Gypsum into the equation. Coots recipe specifically calls for Oyster Shell Flour as a buffer, and includes Crab/Crustacean Meal which also has high calcium content. Coot's worm castings also have a high calcium content due to him using OSF as grit.
If you're inputs are OSF+Crab/Crustacean Meal, you have plenty Calcium and using Gypsum could end up complicating things if you raise your Calcium levels too high.
The issue isn't so much Calcium toxicity, but the fact that you'll experience Mg lockout well before you experience Ca toxicity.
Calcium by nature will also buffer pH, this is why it is common in pretty much every "liming" agent. Odds are, people using a liming agent of some sort (Dolomite Lime/OSF/etc) are more likely to experience issues using Gypsum as opposed to Basalt.
This is also why I stress knowing your inputs.
The issue isn't that Gypsum isn't a great ingredient, it's knowing what it is putting into your soil and how it reacts with your other inputs into the equation.