Be on the watch for algae as well... nothing like root rot/pythium but thrives like a boss in the same conditions that our plants do, highly oxygenated, nutrient rich water, all it needs is a smidge of light to set it off... you can do I did being the seasoned (soil) grower I am... I went out n bought my first flood n drain tray for my first hydro grow and I bought a white table that holds a little water each flood in the channels after it drains that gives algae the perfect place to grow so by the time my weekly res change comes around I have snot on my pumps and hoses etc.... but what I was getting at is it'll fuck with your ph as well... usually up... down u gotta worry about root rot... but even after light proofing all my hoses n went nuts cleaning n bleaching n whatever else... it comes back to the white table being the perfect harbinger of algae so I'm gonna throw some of that weed block stuff over it n hopefully that does it.. but the algae and my hydroton (even after washing it and soaking it 9000 times) drove me ph crazy for the first couple weeks...
I've been using a hydrologic RO maker that has a permeation pump which adds back 15-30ppm of cal/mag after it strips the water of everything... still gotta add some calmag after the fact but not as much...
A bit pricey but it makes 1:1 usable:waste water which is pretty decent since RO is a fairly wasteful setup unless u buy.a decent one... but 130 gallons per day has been enough for me up till recently but I get by with it... I will eventually need to get either a second RO maker or a bigger one in general... but I have mine hooked up to a 55 gallon drum with a float valve that refills as I use it...
http://www.theperfectwater.com/Tap-Master-Artesian-Hydro-Gardener-Pro-Remineralizing-Reverse-Osmosis-Water-Filtration-System.html
I didnt notice if u we're running a sterile res or an organic setup but a sterile res product like h202 is a good investment... there's quite a few products that do the same thing but I like the h202... I run my simple 3 part nutes, blue planet but I just ran out, I use pro-tekt silica, and general organics cal mag... zero veg clones on my first run are looking good even though I am battling the algae issue on and off but plan to have it worked out....
Once you get your nute levels based on plant age/requirements and your water situation straight your ph issues will go away... if u need to adjust up, try using a silica product...down either some cal mag or a small amount of nutes when u top off... RO water is all over the place if u don't know what to expect because it has nothing to hold the ph steady so the most minute amount of ph up or down sends it way in whatever direction which is why I try to use small amounts of nutes....
But good luck man... I have more than 5 years in soil n hydro is like starting new again... I recently moved and my tons of recycled soil that needs mixing etc isn't a possibility so I decided to try hydro going from organic water only soil... talk about a hypocrite.... but good luck.... I know I need it...