Well here is the document that I read prior to the un-vented installation. ... A $50 co sensor put all my fears to rest. Not a peep from it yet. Not even 1 PPM.
1.4.3 Emissions3-4
The emissions from natural gas-fired boilers and furnaces include nitrogen oxides (NOx), carbon
monoxide (CO), and carbon dioxide (CO2), methane (CH4), nitrous oxide (N2O), volatile organic
compounds (VOCs), trace amounts of sulfur dioxide (SO2), and particulate matter (PM).
Nitrogen Oxides -
Nitrogen oxides formation occurs by three fundamentally different mechanisms. The principal
mechanism of NOx formation in natural gas combustion is thermal NOx. The thermal NOx mechanism
occurs through the thermal dissociation and subsequent reaction of nitrogen (N2) and oxygen (O2)
molecules in the combustion air. Most NOx formed through the thermal NOx mechanism occurs in the high
temperature flame zone near the burners. The formation of thermal NOx is affected by three furnace-zone
factors: (1) oxygen concentration, (2) peak temperature, and (3) time of exposure at peak temperature. As
these three factors increase, NOx emission levels increase. The emission trends due to changes in these
factors are fairly consistent for all types of natural gas-fired boilers and furnaces. Emission levels vary
considerably with the type and size of combustor and with operating conditions (e.g., combustion air
temperature, volumetric heat release rate, load, and excess oxygen level).
The second mechanism of NOx formation, called prompt NOx, occurs through early reactions of
nitrogen molecules in the combustion air and hydrocarbon radicals from the fuel. Prompt NOx reactions
occur within the flame and are usually negligible when compared to the amount of NOx formed through the
thermal NOx mechanism. However, prompt NOx levels may become significant with ultra-low-NOx
burners.
The third mechanism of NOx formation, called fuel NOx, stems from the evolution and reaction of
fuel-bound nitrogen compounds with oxygen. Due to the characteristically low fuel nitrogen content of
natural gas, NOx formation through the fuel NOx mechanism is insignificant.
Carbon Monoxide -
The rate of CO emissions from boilers depends on the efficiency of natural gas combustion.
Improperly tuned boilers and boilers operating at off-design levels decrease combustion efficiency resulting
in increased CO emissions. In some cases, the addition of NOx control systems such as low NOx burners
and flue gas recirculation (FGR) may also reduce combustion efficiency, resulting in higher CO emissions
relative to uncontrolled boilers.
Volatile Organic Compounds -
The rate of VOC emissions from boilers and furnaces also depends on combustion efficiency.
VOC emissions are minimized by combustion practices that promote high combustion temperatures, long
residence times at those temperatures, and turbulent mixing of fuel and combustion air. Trace amounts of
VOC species in the natural gas fuel (e.g., formaldehyde and benzene) may also contribute to VOC
emissions if they are not completely combusted in the boiler.
Sulfur Oxides -
Emissions of SO2 from natural gas-fired boilers are low because pipeline quality natural gas
typically has sulfur levels of 2,000 grains per million cubic feet. However, sulfur-containing odorants are
added to natural gas for detecting leaks, leading to small amounts of SO2 emissions. Boilers combusting
unprocessed natural gas may have higher SO2 emissions due to higher levels of sulfur in the natural gas.
For these units, a sulfur mass balance should be used to determine SO2 emissions.
7/98 External Combustion Sources 1.4-3
Particulate Matter -
Because natural gas is a gaseous fuel, filterable PM emissions are typically low. Particulate
matter from natural gas combustion has been estimated to be less than 1 micrometer in size and has
filterable and condensable fractions. Particulate matter in natural gas combustion are usually larger
molecular weight hydrocarbons that are not fully combusted. Increased PM emissions may result from
poor air/fuel mixing or maintenance problems.
Greenhouse Gases -6-9
CO2, CH4, and N2O emissions are all produced during natural gas combustion. In properly tuned
boilers, nearly all of the fuel carbon (99.9 percent) in natural gas is converted to CO2 during the
combustion process. This conversion is relatively independent of boiler or combustor type. Fuel carbon
not converted to CO2 results in CH4, CO, and/or VOC emissions and is due to incomplete combustion.
Even in boilers operating with poor combustion efficiency, the amount of CH4, CO, and VOC produced is
insignificant compared to CO2 levels.
Formation of N2O during the combustion process is affected by two furnace-zone factors. N2O
emissions are minimized when combustion temperatures are kept high (above 1475oF) and excess oxygen is
kept to a minimum (less than 1 percent).
Methane emissions are highest during low-temperature combustion or incomplete combustion, such
as the start-up or shut-down cycle for boilers. Typically, conditions that favor formation of N2O also favor
emissions of methane.