We often believe minerals are responsible for CEC, but
"A metal refers to a chemical element with a relatively low electronegativity (and therefore a donor of electrons) and properties (e.g. electrical and heat conductivity, opacity, metallic luster) conferred by the high mobility of its valence electrons (
Metal - Wikipedia).
A mineral refers to a naturally-occurring crystalline solid of a definite composition (usually formed without the influence of life).
Some metals do occur naturally as crystalline solids in Earth’s crust, and in their “native state”
Mineral definition: A solid inorganic substance of natural occurrence.
Metal definition: A solid material with high electrical conductivity.
"A
native metal is any
metal that is found pure in its metallic form
in nature.
[1][2] Metals that can be found as
native deposits singly or in alloys include
aluminum,
antimony,
arsenic,
bismuth,
cadmium,
chromium,
cobalt,
indium,
iron,
manganese,
molybdenum,
nickel,
niobium,
rhenium,
selenium,
tantalum,
tellurium,
tin,
titanium,
tungsten,
vanadium, and
zinc, as well as the gold group (
gold,
copper,
lead,
aluminium,
mercury,
silver) and the
platinum group (
platinum,
iridium,
osmium,
palladium,
rhodium,
ruthenium). "
"Over geological time scales, very few metals can resist natural weathering processes like
oxidation, so mainly the less reactive metals such as gold and platinum are found as native metals.
The others usually occur as isolated pockets where a natural chemical process reduces a common compound or ore of the metal, leaving the pure metal behind as small flakes or inclusions."
To an extent, metals are actually crucial to a living soil due to their conductivity. No conductivity? No CEC. Period. You will have ZERO CEC without metals/minerals; this is why we add them in the first place.
Metals/minerals are the conduit through which nutrition is able to freely flow.
Lets observe a few examples.
Manganese: a hard brittle silvery metal, often found in
minerals in combination with
iron. Manganese is a
transition metal with a multifaceted array of industrial
alloy uses, particularly in
stainless steels.
Molybdenum: The name is from
Neo-Latin molybdaenum, which is based on
Ancient Greek Μόλυβδος
molybdos, meaning
lead, since its ores were confused with lead ores. Molybdenum does not occur naturally as a
free metal on Earth; it is found only in various
oxidation states in minerals.
Iron: A metal that belongs to the first transition serious and group 8 of the periodic table. In its metallic state, iron is rare in the
Earth's crust, limited mainly to deposition by
meteorites.
Zinc: Zinc is a slightly brittle metal at
room temperature and has a silvery-greyish appearance when oxidation is removed.
Notice how the word "oxidation" frequently pops up. Part of the organic decomposition process. What happens when we let buds sit out in the open air for long enough? Oxidation, which changes things drastically. Oxidation is why we get CBD, the THC oxidizes into various cannabinoids.
Same thing with concentrates. Oxidation will change the texture of your concentrates. Leave shatter out for long enough, it'll wax up on you, why? Oxidation.
Even more interesting, we often hear Mn, Mo, Zn, Fe marketed to us growers as minerals. But, as pointed out above, they are more than simply minerals. They are metals.
Many minerals are also metals. Gold, silver, and copper are also "inorganic substances of natural occurrence". So, by definition, they are minerals. But, they are also metals with high conductivity.
As with anything else,
its about balance, nothing else.
Arsenic is very much a "trigger word" due to it's power as a poison. However, as with any poison, it comes down to PPMs. Fact is, Arsenic is a naturally occurring substance found in many minerals.
It only becomes poisonous when concentrated!
If your soil has Sulfur in it, it likely has traces of Arsenic too that formed naturally.
Arsenic (etc.) content isn't the problem, the quantity is, as well as if things are in balance.
Allow me to use tobacco as another example. Some people can smoke their whole lives, live to be 90, and die of natural causes. Others die before their 40s. While tobacco/nicotine certain is a variable in the equation,
its also about how the recipient of the variable reacts to it.
Speaking of nicotine. Not immediately poisonous when you smoke it in cigarette form, yes? Even a pack a day, likely it takes years for you to die from being a "pack a day smoker".
But, if you took an entire pack of cigarettes, boiled it in water, and then boiled the nicotine infused water down to mere tablespoons. You could take a dropper, fill it with the boiled down nicotine, squirt a couple drops of the concentrated nicotine into someone's coffee. They'll never notice anything "funny tasting", will proceed to have the worst acid trip of their life until they drop dead because of how rapidly their heart begins to beat.
A pack of cigarettes would never cause this reaction on it's own. But concentrated and processed? Different story.
It's not so much the substance, but how it's processed and concentrated!
As always, sorry for the book, and all the best.
tl;dr: metals are naturally occurring and relatively harmless. Concentrated and synthesized metals are the source of any and all issues.