UV sterilization benefits outweight the possible dammage to the solution. I'm sure that there are several variables involved, time the UV sterilizer is used,Output of the UV, how many times the solution is passed over the UV.
When introducing strong oxidiers to a solution, its possible to cause unwanted reactions to the fertilizer. Im still poking at the math at this.. not really my strong point..
Here's a practical example, a commercial greenhouse using UV to sterilize hydroponic solution.
http://dnr.alaska.gov/ag/Grants/ChenaHotSpringsFinalReport2008.pdf