Climate in the 21st Century

Will Humankind see the 22nd Century?

  • Not a fucking chance

    Votes: 44 28.0%
  • Maybe. if we get our act together

    Votes: 41 26.1%
  • Yes, we will survive

    Votes: 72 45.9%

  • Total voters
    157

DIY-HP-LED

Well-Known Member
All other things being equal, price beats every other factor in marketing success, add in increased performance and you've got a winner.


The Next Big Silicon Battery Breakthrough Is So Mysterious

The silicon battery materials startup NEO Energy Materials is playing its next step close to the vest, but driving down the cost of electric vehicles is the plan.

The startup NEO Battery Materials set the Intertubes humming earlier this week when it announced a new mashup with a yet-to-be-named “Top U.S. University Spin-Out.” The agreement is aimed at ratcheting up the performance of NEO’s low-cost silicon battery anode. If all goes according to plan, there will be a huge impact on the cost of electric vehicle batteries. That’s all we know for now, so let the guessing begin: what university did NEO hook up with?

Silicon batteries are lithium-ion batteries tricked out with silicon to replace graphite. Graphite has long been the go-to material for lithium-ion batteries, but silicon offers the allure of longer life and faster charging times along with lower costs, compared to conventional lithium-ion batteries.
The US Army, for one, is silicon-curious. It has been scouting new silicon battery technology on account of the potential for a significant savings on weight, which is an important considerations for soldiers who are loaded with an increasing amount of electronic gear.

Weight savings is also a consideration for the electric vehicle makers. BMW and General Motors are among the list of automakers staking a claim to silicon-based energy storage.

There being no such thing as a free lunch, silicon battery researchers have had to overcome some significant challenges. In a 2017 state-of-play report the US Department of Energy described the main culprit, which involves the instability of the solid electrolyte interphase (SEI).
“The SEI is a film that forms on the anode active particles that inhibits or stops further reactions between the extremely low voltage lithiated anode and the electrolyte,” the Energy Department explained. “Without this film, or with a film that is not sufficiently passivating (as in silicon), these reactions proceed continuously, consuming Li [lithium] and leading to rapid capacity fade and short cell life.”

NEO’s contribution to the field is a set of three silicon anode materials fabricated through a proprietary fabrication process they call “single-step nanocoating.”

“NEO’s products have all achieved an initial coulombic efficiency (ICE) greater than 86%, and high specific capacity (>2500 mAh/g),” NEO expalins. “In addition, an ICE of 92% or higher can be attained when NEO’s silicon is mixed with existing graphite anodes.”

NEO also adds that its technology “significantly improves the life span and cycling stability compared to conventional metallurgical silicon-based particles.” The production line is still phasing up, and as of this writing NEO’s website indicates it is on track to produce its new anode materials at “semi-commercial scale.”


Meanwhile, the newly announced agreement with the yet-to-be-named university is aimed at achieving additional performance improvements by pairing NEO’s silicon anodes with the mystery school’s advanced polymer electrolyte.

NEO also points out that polymer electrolytes are non-flammable, providing for safety improvements.

Though apparently there is more work to be done, NEO is cautiously optimistic. “NEO and the Developer acknowledge that creative, yet fast-paced R&D and collaboration must occur to scale both Parties’ technologies into commercial-level products and outputs,” the company stated in its announcement.

So, who is the lucky top university spin-off? If you have a guess, drop us a note in the comment thread.

There is plenty to guess from. For example, in 2019 a team of researchers at Penn State University reported on their work towards a “supremely elastic gel polymer electrolyte” designed to help stabilize silicon anodes and prevent them from cracking.

A sneak peak at NEO’s silicon battery science advisory board could provide some more clues.

Board member Dr. Jinhyuk Lee, for example, holds degrees from MIT and UC-Berkeley among many (many, many) career achievements. He is currently an assistant professor at McGill University.

Following the trail of academic connections, we see that the Balsara lab at UC-Berkeley specializes in polymer electrolytes.

“Based on our patents, group alumni have cofounded two battery start-up companies: Seeo (founded in 2007) and Blue Current (founded in 2014),” the lab states on its website.

CleanTechnica caught wind of Seeo in 2014 but its energy storage tech hasn’t crossed our radar since 2015, when it was acquired by Bosch. If you have any idea what happened to it, let us know.

Blue Current is new to the CleanTechnica radar, so we have some catching up to do. “The company manufactures 100% dry, safe and high performance silicon elastic composite solid-state batteries to power the new energy economy including electric vehicles, grid storage and consumer electronics,” the company states on its website. It is also hiring, by the way.

The plot thickens when you consider that Blue Current is partners in the Energy Department’s energy storage research hub JCESR, which is short for Joint Center for Energy Storage Research. The consortium launched in 2012 during the Obama administration with Argonne National Laboratory at the helm. In a 2017 recap, JCESR highlighted three startups that leveraged JCESR energy storage properties, including Blue Current as well as the polymer membrane specialist Sepion and the long duration energy storage company Form Energy, which is setting up a new factory in West Virginia.

Still more thickening of the plot occurred last December 22, when Businesswire distributed a press release that apparently speaks for JCESR, Argonne, and Blue Current all at once. The release credits JCESR for enabling Blue Current to “develop a safe, solid-state battery that is ready for megawatt-scale manufacturing.”

The press release notes that Blue Current’s composite electrolyte eliminates the need for metal plates and bolts, and that the target market is electric vehicles.

“As part of rigorous safety testing, the company subjected its cells to harsh conditions that electric vehicles could encounter in the real world. Thermal runaway — an overheating event that can lead to fires — never occurred,” the release emphasizes.

Woke, Schmoke
To be clear, all of this is speculation. Take a look at NEO’s scientific advisory board to see more connections with other top universities in the US, any one of which could have a spinoff in play.

On the other hand, it would be deliciously ironic if Blue Current actually is the to-be-named spinoff hooking up with NEO. That’s because a branch of Koch Industries has put up the big bucks to launch Blue Current’s first factory, a 22,000-square-foot facility to be located in Hayward, California.

That would be the same Koch Industries upon which CleanTechnica has spilled plenty of ink, along with many other news organizations, involving the sprawling company’s fossil energy activities.

Various Koch family members have earned a reputation for fueling right-wing policy making up to and including the US Supreme Court. Koch Industries and its various other branches have also been reportedly funneling money into a multi-state effort to keep “woke capital” from funneling money into renewable energy ventures.

Nevertheless, last year Koch Strategic Platforms announced a $30 million investment in Blue Current.

Blue Current’s proprietary battery maximizes safety and performance, stabilizes temperature, and enables greater scalability across uses,” KSP noted in a press release dated April 22, 2022. “The fully dry high silicon elastic composite battery combines the mechanical properties of polymers with the ionic conductivity of glass ceramics.”

The announcement also cited KSP managing director Jeremy Bezdek, who said, “Solid-state battery technology will play a pivotal role in global energy transformation.”

“Our extensive diligence indicated that Blue Current has an advantaged intellectual property position that has the potential to be disruptive in the solid-state battery space,” Bezdek added.

It all makes sense when you consider that KSP has also invested in the startup REE, which plans to make waves with a flexible, skateboard-style electric vehicle platform.

Go figure.
 

DIY-HP-LED

Well-Known Member
Mississippi passes bill restricting electric car dealerships
They might as well piss against the wind the result will be much the same. There is a reason every carmaker on the planet has bet the farm on EVs and battery factories are popping up all over America and it isn't just subsidies. It is a paradigm shift in the auto industry that will happen over the next decade, and it is a simple case of adapt or die. Demand for EVs is already outstripping production, even in this sorry early state of battery development. However, EVs should be long lived, if the battery pack is replaced by a cheaper, better after market battery pack and that is already happing for some older EVs.
 

DIY-HP-LED

Well-Known Member

Solar Breakthroughs Suggest Perovskite’s Day In The Sun Is Almost Here
The last two weeks have seen three announcements regarding the solar cell technology known as perovskites, any of which could transform electricity production if they can be replicated at scale.

Perovskite solar cells have developed extraordinarily fast, going from a curiosity to the hottest area of solar research in the space of a few years. After overcoming a series of barriers one major problem has remained; their durability. A paper in Nature Materials reports a novel solution. It comes less than a fortnight after two other potentially equally significant papers, one providing an alternative solution to the same problem and the other indicating perovskites are even more exciting than anyone knew.

The vast majority of photovoltaic cells in operation in the world are made using silicon. Although the raw material is among the cheapest and most abundant on Earth, the high temperatures needed to produce ultra-pure polysilicon require substantial energy input. Despite the spectacular fall in prices for silicon cells over the last 50 years, it is widely believed that to go much further we will need something different. Many alternatives have been tried, and some have proven better than silicon in certain niches, but only perovskites have looked likely to become a major source of power in the world.

Perovskites are named after the natural material whose basic structure they mimic. They are made up of calcium, oxygen, and titanium – all very cheap elements – doped with metals. The quantity of metals used is so small that manufacturing costs should be very low. Moreover, where silicon cells are good at collecting energy from the red part of the spectrum but bad at the blue, perovskites can be tuned to suit desired wavelengths.

Ion migrations have posed a problem for previous efforts to commercialize perovskite cells because the migrating ions make the material unstable and lead to long-term breakdown. Even very cheap solar cells are not much use for most purposes if they don’t last long. A team led by Professor Aram Amassian of North Carolina State University have now described a way to “corral” ions within perovskites to control these migrations.

“We have not found a way to prevent ions from moving through perovskite materials, but we have found that it is possible to steer these ions into a safe conduit that does not impair the material’s structural integrity or performance,” Amassian said in a statement. “It’s a big step forward.”

Perovskites are produced as a series of crystals or “grains”, which touch at grain boundaries. “Grains are better protected from impairment when the ions move predominantly along the grain boundary,” said first author Masoud Ghasemi.

By managing the boundaries, the team have shown it is possible to make perovskites more stable.

As if extending the lifespan of clean generators were not enough, Amassian believes there is potential for the corralling work to be applied to other sorts of crystalline charge carriers, which could lead to improved electricity storage devices.

Two weeks earlier a paper in Science described another way to stabilize perovskites for long-term use, by treating them with 1,3-bis(diphenylphosphino)propane (DPPP). Despite its formidable name, "DPPP is also a commercialized product with low cost and easy accessibility,” said author Dr Zhaoning Song of the University of Toledo in a statement.

Yet another paper, also published during this epic two weeks, doesn’t address perovskites’ stability but instead demonstrates they can be even more efficient at turning sunlight into electricity. Perovskite cells are so thin they are placed on substrates to give them stability, and this has usually been glass.

However, Professor Chunlei Guo and colleagues at the University of Rochester found perovskites on metal or dielectric substrates harvest 30-50 percent more of the energy in light falling on them. The excitation of electrons also lasts much longer, offering more time in which they can be tapped. “No one else has come to this observation in perovskites,” Guo said in a statement. “All of a sudden, we can put a metal platform under a perovskite, utterly changing the interaction of the electrons within the perovskite.”

Moreover, by alternating metal and dielectric layers, he reports in Nature Photonics, the sensitivity of photodetectors can be increased an astonishing 250 percent.

All three teams still need to demonstrate their ideas work at scale and outside specialized laboratory conditions. Guo may also find alternating substrates adds too much to the cost of cell production to make the approach useful outside specialist environments where efficiency matters more than price.

However, if even one of the approaches makes the jump from lab bench to mass production, they could wipe out fossil fuel use during daylight hours, saving consumers money at the same time.

The papers are published in Nature Materials (open access), Science, and Nature Photonics (open access).
 

CANON_Grow

Well-Known Member
They might as well piss against the wind the result will be much the same. There is a reason every carmaker on the planet has bet the farm on EVs and battery factories are popping up all over America and it isn't just subsidies. It is a paradigm shift in the auto industry that will happen over the next decade, and it is a simple case of adapt or die. Demand for EVs is already outstripping production, even in this sorry early state of battery development. However, EVs should be long lived, if the battery pack is replaced by a cheaper, better after market battery pack and that is already happing for some older EVs.
This isn't to try and prevent EV sales, it just doesn't allow EV manufacturers to sell directly to consumers via manufacturer owned brick and mortar dealerships. This is to mandate EV's must be sold by a dealership with a franchise agreement or only online if direct from manufacturer. I actually think it is a pretty wise move that encourages competition and helps to prevent a monopoly from becoming established. Lots of horror stories regarding Tesla's service and crazy pricing for repairs, having competing dealers should keep that to a minimum.
 

DIY-HP-LED

Well-Known Member
This isn't to try and prevent EV sales, it just doesn't allow EV manufacturers to sell directly to consumers via manufacturer owned brick and mortar dealerships. This is to mandate EV's must be sold by a dealership with a franchise agreement or only online if direct from manufacturer. I actually think it is a pretty wise move that encourages competition and helps to prevent a monopoly from becoming established. Lots of horror stories regarding Tesla's service and crazy pricing for repairs, having competing dealers should keep that to a minimum.
It appears to be anti Elon! :lol: However there is a reactionary streak in the GOP to green energy, but it's taken a hit recently with all the new battery factories going up. The idea of individual energy and transportation independence appeals to many rural types where power rates are often higher. Also, wind farms and solar can provide rural incomes and you can farm, or graze land used for wind power. You can even graze sheep to keep the plants down around solar farms too, or space them out for dual use.
 

Roger A. Shrubber

Well-Known Member
this is interesting

why don't governments have these discussions before they make decisions? seems like they'd save a lot of wasted time and effort, and avoid a lot of bad sentiment, if they just talked to those involved before they made their determinations...
 

cannabineer

Ursus marijanus
why don't governments have these discussions before they make decisions? seems like they'd save a lot of wasted time and effort, and avoid a lot of bad sentiment, if they just talked to those involved before they made their determinations...
I suspect that it illustrates just how new the idea is that indigenous peoples have territorial rights. Even in places that we associate with a liberal attitude.
 

Sativied

Well-Known Member
I suspect that it illustrates just how new the idea is that indigenous peoples have territorial rights. Even in places that we associate with a liberal attitude.
“Indigenous people in Europe? Lol, like indians?” sums up the typical response here. If it weren’t for scandinavian tv (they have pretty good movies and mini-series), I wouldn’t have know about the Sami either.

Personally I think Gretha’s good intentions don’t help the cause. I’m saying this mostly cause family in australia and rural areas in NL bring her up frequently to ridicule everything related to climate change.
 

DIY-HP-LED

Well-Known Member
“Indigenous people in Europe? Lol, like indians?” sums up the typical response here. If it weren’t for scandinavian tv (they have pretty good movies and mini-series), I wouldn’t have know about the Sami either.

Personally I think Gretha’s good intentions don’t help the cause. I’m saying this mostly cause family in australia and rural areas in NL bring her up frequently to ridicule everything related to climate change.
She's a kid and people her age have always protested something or other. How do the natives feel about the wind turbines and do they really represent a hazard to them. What legal claims do they have etc.
 

DIY-HP-LED

Well-Known Member
A place like Tahoe is in chaos over snow? isn't snow half of their livelihood?
A place that gets at least half of it's income from skiing is paralyzed because they got snow?....?
They got a lot of snow, Donner Party levels of snow, they might turn to cannibalism if they don't get out by spring! :lol:
 
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DIY-HP-LED

Well-Known Member

How To Make Bricks From Plastic Trash | World Wide Waste | Insider Business

584,151 views Feb 25, 2023 #WorldWideWaste #PlasticBricks #InsiderBusiness
A company shreds, melts, and molds a secret mixture of hard-to-recycle plastics to make solid bricks and beams. The building materials are cheaper and faster to assemble than most traditional ones. The system has helped increase waste collectors' income and address a shortage of school buildings in Ivory Coast.
 

cannabineer

Ursus marijanus
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