@k0ijn:
"THC can degrade into CBN, THC-A can't."
True, but you knew what I meant:
Some THC-A will become THC, which is a well known fact. Therefore some of the THC-A ends up as CBN, during drying & curing.
I never accused YOU for lack of sources in your posts on rollitup forums.
I don't know you, so I didn't know if you simply repeated forum-noise or not, which the majority do.
So I simply asked for the source of a SINGLE statement you wrote, I never even claimed it was wrong:
"Amber trichomes contain CBN which is the product of degraded THC and it represents a 90% loss of potency."
I never got the source from you.
The fact that THC-A becomes THC and that the THC can degrade into CBN does not relate to THC-A becoming CBN directly.
You can't just say that because CBN is the degradation product of THC then the precursor to THC, THC-A, ends up as CBN during drying & curing.
CBN is not just formed during drying & curing.
CBN can be formed due to bad conditions, light exposure and it's also formed continuously during the plants life by regular 'ageing' of trichomes, if you will.
It seems to me that you think fresh plants contain only THC-A and CBN is only formed during drying & curing.
I don't know why you have come to that conclusion but it's not correct.
This is a quote from you:
"
Rember THC-A (which fresh plants are fulll of)?
The THC-A which will eventually get formed into regular THC automatically over time (or using ligher in a bong (heat)).
BUT, THC-A will ALSO form CBN! (and everybody seem to hate CBN)."
Those statements are so misleading and show a lot of misunderstanding of which substances are formed when and how the degrade / reform into other substances.
I know you wanted that and my response will be exactly the same as it was before;
If you look through my posts on this subject you will see me referencing sources, including books, biotech companies, theses & research.
Instead of saying I talk bullshit straight away why didn't you just do a simple search and look at the sources presented?
Why do I have to source every repeat statement I make when I have already sourced the original argument in previous posts, readily available?
These are some of the sources I have mentioned numerous times in many different posts, most recently the trichome post:
Cannabinoid synthesis, pharmacology etc:
Books:
Cannabid and Cannabinoids:
Pharmacology, Toxicology, and Therapeutic Potential
Marijuana Chemistry:
Genetics, Processing And Potency
montanabiotech.com
And I wrote that the pathways (the forming of THC etc) are not know for certain yet, there are currently at least two widely accepted views.
Wikipedia:
"
Cannabinoid production starts when an enzyme causes geranyl pyrophosphate and olivetolic acid to combine and form CBG.
Next, CBG is independently converted to either CBD or CBC by two separate synthase enzymes. CBD is then enzymatically cyclized to THC. For the propyl homologues (THCV, CBDV and CBNV), there is a similar pathway that is based on CBGV. (recent studies show that THC is not cyclized from CBD but rather directly from CBG. no experiment thus far has turned up an enzyme that converts CBD into THC although it is still hypothesized.)
"
Like I said, there are conflicting info out there even among scholars - science still has a lot to figure out.
Science has a lot to figure out but it also knows a lot about cannabinoids already, which is generally viewed as fact.
The science behind the synthesis of cannabinoids has been known for a while and is agreed upon.
There might be some uncertaincies with regards to the relationship of the -A & -V cannabinoids but the syntheses of the seperate THC - CBD - CBC etc are quite well known.
I'm not sure why you quote a section of wikipedia (and a section which has no references or sources) as a credible source but that is your call.
In fact I can point out a very obvious mistake in the wikipedia quote you made;
"...geranyl pyrophosphate and olivetolic acid combine and form CBG."
That's not the case. Geranyl pyrophosphate & Olivetolic acid combine to form CBG-A (the precursor acid which forms CBG).
And the crux of the point in:
"
(recent studies show that THC is not cyclized from CBD but rather directly from CBG. no experiment thus far has turned up an enzyme that converts CBD into THC although it is still hypothesized.)"
is rather lost due to the fact that the wrong cannabinoids are mentioned.
The wikipedia section you quoted has skipped a lot of steps (or more likely; the person who wrote it on wikipedia does not really have a firm grasp of the processes).
THC is in _some_ way formed by CBG but not directly, not at all.
THC-A is derived from CBG-A, and THC is in turn derived from THC-A. Thus they are connected in a pathway if you will, but saying:
"
THC... (is formed)...directly from CBG."
Is just false and misleading.
I hope you can see the point I'm trying to make.
A lot of steps have been skipped, and it could well be the confusion.
If you look in my post on trichomes:
https://www.rollitup.org/harvesting-curing/516184-trichomes-harvesting.html
You will find an image which explains rather well how different cannabinoids form and which paths they take.
That image is taken from a Biotech company who focus all their research on cannabis and cannabinoids in particular.
And in any case, I'll trust scientific research done by professionals over a wikipedia notation without references or sources.
And anyway you are now shifting the arguments over to something different.
The reason why I haven't responded to the stuff you wrote about CBD & THC interaction is that;
The relationship between CBD & THC was not questioned by me or anyone else.
The information you posted regarding how THC & CBD interacts has already been posted numerous times on these forums and most serious growers know of it.
There is nothing to have a discussion about there, you're simply stating facts which no one has argued against.
I agree with you on the interaction of cannabinoids but that was not a point of the original discussion and it's irrelevant.