Plants have both a dark and light cycle. Photosynthesis produces sugars and that's it. These sugars are then broken down during the dark cycle (krebs cycle) to produce everything else the plant needs - fats, esthers, proteins, cell replication, root and foliage growth, even the production of more chloroplasts so that the plant better utilized light during the light phase.
The krebs cycle takes place regardless of whether there is an actual dark period or not but at a different rate. These are figurative numbers so when you get around to looking up the real ones in a text book don't yell at me - the plant has a cap on how much it can do at one time which we will call 100%. During the light phase the plant dedicates ~70% of its energy towards photosynthesis (the production of sugar onto which plants imbed electrons for later use). The remaining 30% of its energy is used in the krebs cycle to break down these sugars to get at the stored electrons and to use them for DNA/RNA replication, cell division, protein synthesis, auxin creation...
During the night there is no light and thus the plant cannot dedicate 70% of its energy into photosynthesis and thus switches over to the krebs cycle to break down the sugars it produced during the day and actually get work done. Lets pretend the plant is a car. If you sat all day long pumping gas into it you would have a ton of gas which is great as you have a ton of potential energy - unfortunately if you never stopped pumping gas to actually drive the car the gas really does you no good. It's better to just refill the tank when it's empty and drive the car the rest of the time.
If you really want to do some science setup your own experiment with one plant under 24hrs and one under 18. I have done this several times and must say there is a huge difference in growth rates in favor of the 18hrs. If you really can't decide then run it at 21hrs and compromise
And fuck Ed Rosenthal, I've never seen a single bit of science from him or Jorge Cervantes - people need to pick up text books with actual science before they reach for a book written by pot heads (even if he is a famous one). Great if you want to memorize a recipe but terrible if you want to be able to formulate your own.