the hammerhead and the pk 13/14 are pretty much the same thing... i know AN claims that changing the number from 13/14 to 9/18 is a big difference, but it is really not. I have used both products and they both work well, but after some tests, i decided to stick to the pk 13/14 because it is the very highest grade PK u can possibly get (Pharmaceutical Grade) and it is half the price of AN. (i have no idea of the grade of AN's Hammerhead PK, i know some of their products are pharmuceutical grade tho)
The PK in those higher amounts is only being utilized by the plant for about a 7-14 day window. The reason that AN and Canna both tell you to use it for longer is bcuz every strain has a different "window" of time that the high PK is beneficial, and they want to make sure you are using it when that window opens... but also, the longer you use it, the more you will use, and the more you will BUY! I think its a little misleading for AN to tell you to use it so early and so late into flowering because it is very unlikely that the "PK window" would be open at those times.
PK tends to be best used in a 7 - 10 day window starting about the time you see first flower formation. This typically, on an 8 week flower response group, to be about 5 weeks before harvest or 2-3 weeks after flower initiation (not light change). Adding it early will not advance or benefit flower initiation, only the amount of dark the plant sees will initiation flowering. Adding too early could result in phosphate accumulation and ratio issues involving Ca and Mg
The best way to dial in the PK takes some trial and error work. This can be anything from 3 - 10 days after switching light cycle or the natural trigger for flower is received by the plant. Remember a plant has to convert to flower in most cases which takes a little time from the moment the dark cycle increases or decreases based on the species of plant being grown. Use PK for about a 3 week window at each irrigation along with the other components. Then you can stop. You really can not use PK too long except in the final week or so, or giving it too early. The next crops, you can begin to shorten the beginning or end of the window until you find that just right window for your needs.
Oh, and Ionic is a good company as well, so i doubt you will see any huge difference from the switch.